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A cobalt-free SrFe0.9Sb0.1O3−δ cathode material for proton-conducting solid oxide fuel cells with stable BaZr0.1Ce0.7Y0.1Yb0.1O3−δ electrolyte
- Source :
-
Journal of Power Sources . Oct2010, Vol. 195 Issue 20, p7042-7045. 4p. - Publication Year :
- 2010
-
Abstract
- Abstract: A cobalt-free cubic perovskite oxide SrFe0.9Sb0.1O3−δ (SFSb) is investigated as a novel cathode for proton-conducting solid oxide fuel cells (H-SOFCs). XRD results show that SFSb cathode is chemically compatible with the electrolyte BaZr0.1Ce0.7Y0.1Yb0.1O3−δ (BZCYYb) for temperatures up to 1000°C. Thin proton-conducting BZCYYb electrolyte and NiO–BaZr0.1Ce0.7Y0.1Yb0.1O3−δ (NiO–BZCYYb) anode functional layer are prepared over porous anode substrates composed of NiO–BZCYYb by a one-step dry-pressing/co-firing process. Laboratory-sized quad-layer cells of NiO–BZCYYb/NiO–BZCYYb/BZCYYb/SFSb are operated from 550 to 700°C with humidified hydrogen (∼3% H2O) as fuel and the static air as oxidant. An open-circuit potential of 0.996V, maximum power density of 428mWcm−2, and a low electrode polarization resistance of 0.154Ωcm2 are achieved at 700°C. The experimental results indicate that the cobalt-free SFSb is a promising candidate for cathode material for H-SOFCs. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 195
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 51844927
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2010.05.015