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Dissecting a Dyotropic Rearrangement.
- Source :
-
Journal of Organic Chemistry . 3/5/2010, Vol. 75 Issue 5, p1693-1700. 8p. 12 Diagrams. - Publication Year :
- 2010
-
Abstract
- Herein we describe density functional theory calculations on nitroso acetal-to-aminal rearrangements reported by Denmark and co-workers. Our calculations indicate that various structural (ring strain, hyperconjugation, anomeric effects) and environmental (both specific and nonspecific solvation) factors greatly influence the ease of rearrangement. Our calculations also indicate that both concerted and stepwise mechanisms are energetically viable. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 75
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 49172803
- Full Text :
- https://doi.org/10.1021/jo902685x