Radiative transfer modeling of filter-based measurements of light absorption by particles: Importance of particle size dependent penetration depth

Abstract: We present new physical models to interpret the response characteristics of filter-based measurements of aerosol light absorption. They were motivated by a recently found particle size dependence of a systematic bias in absorption measurements that cannot be interpreted by any models reported thus far. A theory of particle filtration by fibrous filter is applied to reproduce the penetration depth of particles into a filter matrix, and the light transmissivity of the matrix is calculated by the use of radiative transfer theory for plane-parallel layers. Optical properties of individual layers are calculated from microphysical properties and the number density of filter fibers and deposited particles. The size-dependent systematic bias in absorption measurement is successfully explained by the particle size dependence of penetration depth into a filter matrix. In practice the physical models developed here are useful for selecting operating conditions and filter matrices for instruments with fewer systematic biases. [Copyright &y& Elsevier]