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Synthesis of functionalized α-CF3-α-aminophosphonates via Cu(I)-catalyzed 1,3-dipolar cycloaddition

Authors :
Vorobyeva, Daria V.
Karimova, Natalya M.
Vasilyeva, Tamara P.
Osipov, Sergey N.
Shchetnikov, Grigory T.
Odinets, Irina L.
Röschenthaler, Gerd-V.
Source :
Journal of Fluorine Chemistry. Mar2010, Vol. 131 Issue 3, p378-383. 6p.
Publication Year :
2010

Abstract

Abstract: A convenient method for the preparation of α-CF3-α-aminophosphonates bearing alkynyl group at the α-carbon atom has been described. New alkynylphosphonates have been further utilized in the synthesis of functionalized triazole-containing α-CF3-α-aminophosphonates via copper-catalyzed (3+2)-cycloaddition to different organic azides. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00221139
Volume :
131
Issue :
3
Database :
Academic Search Index
Journal :
Journal of Fluorine Chemistry
Publication Type :
Academic Journal
Accession number :
48260728
Full Text :
https://doi.org/10.1016/j.jfluchem.2009.12.003