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The Missing Link Between Molecular Triplets and Spin-Polarized Free Radicals: Room Temperature Triplet States of Nanocrystalline Radical Pairs.

Authors :
Lebedeva, Natalia V.
Tarasov, Valery F.
Resendiz, Marino J. E.
Garcia-Garibay, Miguel A.
White, Ryan C.
Forbes, Malcolm D. E.
Source :
Journal of the American Chemical Society. 1/13/2010, Vol. 132 Issue 1, p82-84. 3p.
Publication Year :
2010

Abstract

The article discusses the examination of nanocrystalline radical pair triplet state by laser flash photolysis of dicumylketone analogue. It cites results such as occurrence of triplet state time-resolved electron paramagnetic resonance (TREPR) spectra at room temperature. It adds that electron dipole-dipole interactions influenced triplet states' magnetic properties. It notes that photoexcited molecular triple states of dicumyl ketone are examined at low temperatures in dilute frozen matrices.

Details

Language :
English
ISSN :
00027863
Volume :
132
Issue :
1
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
48230196
Full Text :
https://doi.org/10.1021/ja909521u