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The stress tensor in thermodynamics and statistical mechanics.

Authors :
Rossi, G. C.
Testa, M.
Source :
Journal of Chemical Physics. 2/21/2010, Vol. 132 Issue 7, p074902. 3p.
Publication Year :
2010

Abstract

We prove that the stress tensor, τab, of a molecular system with arbitrary, short-range interactions can be point-wisely expressed as the functional derivative of the partition function with respect to the local deformation tensor. In this approach, the set of components of τab has a simple interpretation as the set of Lagrangian multipliers which one needs to introduce to enforce the conditions relating point particle displacements to the body local deformation tensor. The question of the possible nonuniqueness of the formula for τab is discussed. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
132
Issue :
7
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
48199717
Full Text :
https://doi.org/10.1063/1.3316134