Low temperature H2-SCR over platinum catalysts supported on Ti-containing MCM-41

Abstract: A series of Ti-containing MCM-41 were prepared by isomorphously substitution, wet impregnation and mechanical mixing. Ti-containing MCM-41 materials, together with reference Si–MCM-41, were characterized by means of XRD, TEM and low temperature N2 adsorption/desorption. The nature of Ti species on Ti-containing MCM-41 was analyzed by means of UV–vis and Raman spectroscopy. Pt catalysts supported on Si–MCM-41 and Ti-containing MCM-41 were studied for the selective catalytic reduction of NO by hydrogen in excess oxygen. Particular attention was paid to the promotion effect of different Ti species on the catalytic activity for H2-SCR and the origin thereof. Pt/Ti–MCM-41 prepared by wet impregnation with the Ti/Si ratio of 0.6 exhibited the best activity and ca. 89% NOx conversion as well as ca. 79% N2 selectivity, could be achieved at 140°C with a feed stream containing 1000ppm NO, 5000ppm H2, 6.7% O2 at a high GHSV of 80,000h−1. Moreover, Pt–Ti–MCM-41 exhibited good duration and good tolerance to co-existing 20ppm SO2 or 50ppm CO, which demonstrated its potential for future applications. [Copyright &y& Elsevier]