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Three new coordination polymers based on 4-oxo-1(4H)quinolineacetate: Synthesis, structures and luminescent properties
- Source :
-
Inorganic Chemistry Communications . Feb2010, Vol. 13 Issue 2, p322-325. 4p. - Publication Year :
- 2010
-
Abstract
- Abstract: Reactions of 4-oxo-1(4H)-quinolineacetic acid (Hoqa) and varied metal salts of Zn(II), Cd(II) and Ag(I) resulted in the formation of three new coordination polymers, namely, [Zn(oqa)2]·H2O (1), [Cd(bpy)(oqa)2(H2O)2]·4H2O (2) and [Ag(bpy)(oqa)]·2H2O (3) (bpy=4,4′-bipyridine). Complex 1 has a three-dimensional (3D) polymeric network with diamondoid topology; compounds 2–3 exhibit one-dimensional (1D) chain structure characteristics, which are further assembled through π–π stacking attractions and hydrogen bonds, forming the 3D supramolecular frameworks. In addition, the solid-state luminescent properties of the ligand Hoqa and complexes 1–2 have been investigated at room temperature. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 13
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 47646866
- Full Text :
- https://doi.org/10.1016/j.inoche.2009.12.015