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A BondâBond Description of the Intermolecular Interaction Energy: The Case of the Weakly Bound AcetyleneâHydrogen Complexâ.
- Source :
-
Journal of Physical Chemistry A . Dec2009, Vol. 113 Issue 52, p14867-14874. 8p. - Publication Year :
- 2009
-
Abstract
- A new semiempirical potential energy surface (PES) for the acetyleneâhydrogen system has been derived by using the recently introduced bondâbond methodology. The proposed PES, expressed in an analytic form suitable for molecular dynamics simulations, involves a limited number of parameters, each one having a physical meaning and allowing the accurate description of the system also in the less stable configurations. The analysis of novel integral cross sections data, measured with nearly effusive molecular beams, combined with that of available pressure broadening coefficients of isotropic Raman lines at 143 K and IR lines at 173 and 295 K of C2H2in H2, provides a test of the reliability of the proposed PES and suggests also some refinements. An extensive comparison with a recent ab initio potential is also exploited. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10895639
- Volume :
- 113
- Issue :
- 52
- Database :
- Academic Search Index
- Journal :
- Journal of Physical Chemistry A
- Publication Type :
- Academic Journal
- Accession number :
- 47343838
- Full Text :
- https://doi.org/10.1021/jp905055n