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Nonenzymatic Kinetic Resolution of Secondary Alcohols: Enantioselective S[sub N]2 Displacement of...

Authors :
Sekar, Govindasamy
Nishiyama, Hisao
Source :
Journal of the American Chemical Society. 04/18/2001, Vol. 123 Issue 15, p3603. 2p. 3 Charts.
Publication Year :
2001

Abstract

Investigates the nonenzymatic kinetic resolution of secondary alcohols. Enantioselective S[sub 2] displacement of hydroxy groups by halogens in the presence of chiral BINAP; Role of enantiopure alcohols for the synthesis of a wide range of natural products, chiral ligands and biologically active compounds.

Details

Language :
English
ISSN :
00027863
Volume :
123
Issue :
15
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
4696238
Full Text :
https://doi.org/10.1021/ja010029i