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Unexpected Multiple Electrophilic Addition Reaction of (Z)-Alk-2-en-4-ynoates with N,N-Dibromo-p-toluenesulfonamide (TsNBr2): A Highly Diastereoselective Synthesis of Densely Functionalized Aziridines.

Authors :
Ruwei Shen
Xian Huang
Source :
Organic Letters. Dec2009, Vol. 11 Issue 24, p5698-5701. 4p.
Publication Year :
2009

Abstract

A novel electrophilic addition reaction of (Z)-alk-2-en-4-ynoates and TsNBr2is reported, providing a facile and highly stereoselective synthesis of densely functionalized aziridine derivatives. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15237060
Volume :
11
Issue :
24
Database :
Academic Search Index
Journal :
Organic Letters
Publication Type :
Academic Journal
Accession number :
46836008
Full Text :
https://doi.org/10.1021/ol902446h