Synthesis, structure characterization and fluorescence property of a new fluoride borate crystal, CdZn2KB2O6F

Abstract: A new fluoride borate crystal, CdZn2KB2O6F, has been synthesized by flux-supported solid-state reaction. The crystal structure has been determined by single-crystal X-ray diffraction. It crystallizes in the trigonal space group with a=5.0381(6)Å, b=5.0381(6)Å, c=15.1550(19)Å, α=90.00°, β=90.00°, γ=120.00°, Z=2. The crystal represents a new structure type in which ZnBO3 layers are connected through bridging fluorine and cadmium atoms alternately along the c-axis. K+ cations are filled in the intralayer open channels to balance charge. IR and Raman spectra further confirm the crystal structure. Photoluminescent measurement reveals that CdZn2KB2O6F exhibits blue fluorescence at room temperature in the solid-state. [Copyright &y& Elsevier]