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Stereo- and Regioselective Nucleophilic Addition to Dihapto-Coordinated Pyridine Complexes.

Authors :
Daniel P. Harrison
Victor E. Zottig
George W. Kosturko
Kevin D. Welch
Michal Sabat
William H. Myers
W. Dean Harman
Source :
Organometallics. Oct2009, Vol. 28 Issue 19, p5682-5690. 9p.
Publication Year :
2009

Abstract

A dihapto-coordinated pyridine ligand of a tungsten complex is readily alkylated or acylated at nitrogen, and the resulting pyridinium species undergoes regio- and stereoselective addition at C2 with a wide range of nucleophiles. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
02767333
Volume :
28
Issue :
19
Database :
Academic Search Index
Journal :
Organometallics
Publication Type :
Academic Journal
Accession number :
44778913
Full Text :
https://doi.org/10.1021/om900637x