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2D water layer enclathrated between Mn(II)–Ni(CN)4 coordination frameworks
- Source :
-
Journal of Solid State Chemistry . Oct2009, Vol. 182 Issue 10, p2608-2612. 5p. - Publication Year :
- 2009
-
Abstract
- Abstract: A [Ni(CN)4]2−-based two-dimensional Mn(II) coordination polymer {Mn(H2O)2[NiCN]4·4H2O}, in which the coordination layers are stacked on top of each other sandwiching 2D water layer of boat-shaped hexagonal water clusters has been synthesized. The complex exhibits high thermal decomposition temperature and reversible water absorption, which were clearly demonstrated by thermal and PXRD studies on the parent and rehydrated complex after dehydration. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00224596
- Volume :
- 182
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Journal of Solid State Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 44484135
- Full Text :
- https://doi.org/10.1016/j.jssc.2009.05.014