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Photoactivation of Ruthenium Olefin Metathesis Initiators.
- Source :
-
Organometallics . Aug2009, Vol. 28 Issue 16, p4652-4655. 4p. - Publication Year :
- 2009
-
Abstract
- UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro−trans-dichloro photoisomerization. The enhanced activity of the trans isomer, when aromatic substituents were attached to the sulfur chelating atom, induced several metathesis reactions, including ROMP, at room temperature. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02767333
- Volume :
- 28
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- Organometallics
- Publication Type :
- Academic Journal
- Accession number :
- 44221510
- Full Text :
- https://doi.org/10.1021/om9004302