Back to Search
Start Over
Synthesis, characterization and electrochemical properties of a novel triphosphate LiFe2P3O10
- Source :
-
Electrochimica Acta . Sep2009, Vol. 54 Issue 23, p5500-5508. 9p. - Publication Year :
- 2009
-
Abstract
- Abstract: A novel lithium iron phosphate has been synthesized by a solution route at moderate temperature. The structure was determined from powder by XRD, HRTEM and SAED experiments. LiFe2P3O10 tripolyphosphate crystallizes in the monoclinic system, space group P21 /m, with lattice constants a =4.597(7)Å, b =8.566(4)Å, c =9.051(4)Å, β =97.47° and Z =2. Internal and external vibrational modes (Raman and FTIR) show that the dominant spectral features come from the (P3O10)5− oxo-anions displaying internal and external modes along with the P–O–P bridging modes. Magnetic measurements are consistent with the high-spin configuration of Fe2+ cation with an effective magnetic moment 5.51μB. A weak antiferromagnetic ordering is observed below the Néel temperature at T N =19K. Electron paramagnetic resonance spectroscopy confirms this electronic configuration and provides evidence of the presence of a carbonaceous layer onto the particle surface. Electrochemical measurements were carried out in lithium cells with LiPF6–EC–DEC electrolyte at 25°C. The material delivered a capacity 70mAh/g in the voltage range 2.7–3.9V, close to the theoretical value (72mAh/g). The resulting cyclic voltammogram indicates a stable structure with a good reversibility with the redox peaks at 3.26 and 3.13V vs. Li0/Li+. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 54
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 42965585
- Full Text :
- https://doi.org/10.1016/j.electacta.2009.04.050