Photodissociating trimethylamine at 193 nm to probe dynamics at a conical intersection and to...

Reports on crossed laser-molecular beam scattering experiments measuring the photofragment velocities and product branching in the photodissociation of trimethylamine at 193 nanometer. Observation of two primary N-CH[sub 3] bond fission channels; Contribution of a third minor channel to the dissociation dynamics; Calibration of mass spectrometry sensitivity.