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Rhodium catalyzed enantioselective cyclization of substituted imidazoles viaCâH bond activationThis article is part of a ChemComm âCatalysis in Organic Synthesisâ web-theme issue showcasing high quality research in organic chemistry. Please see our website http:www.rsc.orgchemcommorganicwebtheme2009 to access the other papers in this issue.Electronic supplementary information (ESI) available: Experimental details, analytical data, HPLC chromatograms, NMR spectra, and X-ray crystallographic data. CCDC 727522. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b902878a
- Source :
-
Chemical Communications . Jul2009, Vol. 2009 Issue 26, p3910-3912. 3p. - Publication Year :
- 2009
-
Abstract
- The enantioselective intramolecular alkylation of substituted imidazoles with enantiomeric excesses up to 98 has been accomplished by rhodium catalyzed CâH bond functionalization with S,Sâ²,R,Râ²TangPhos as the chiral ligand. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 2009
- Issue :
- 26
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 42425503
- Full Text :
- https://doi.org/10.1039/b902878a