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Calculated and experimental rotational constants of (D[sub 2]O)[sub 3]: Effects of intermolecular...

Authors :
Sabo, Dubravko
Bacic, Ziatko
Source :
Journal of Chemical Physics. 9/22/1999, Vol. 111 Issue 12, p5331. 7p. 4 Diagrams, 5 Graphs.
Publication Year :
1999

Abstract

Presents calculations of the torsional state dependence of A = B and C rotational constants of (D[sub 2]O)[sub 3], for torsional energies of up to 100 cm [sup -1] above the ground state. Changes of rms torsional angles of the 'free' O-D bonds; Changes in the oxygen-oxygen separation which accompany torsional excitation.

Details

Language :
English
ISSN :
00219606
Volume :
111
Issue :
12
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
4190761
Full Text :
https://doi.org/10.1063/1.479792