Plasma synthesis of tungsten carbide and cobalt nanocomposite powder

Abstract: Nanosized tungsten carbide–cobalt composite powder was synthesized by a thermal plasma process, in which ammonium paratungstate (APT) and cobalt oxide were reacted with a gas mixture containing CH4, H2, and Ar. The reduction and carburization of vaporized precursors produced nanosized tungsten carbide (WC1−x )–cobalt composite powder, which contained small amounts of W2C and/or W phase. The particle size of synthesized tungsten carbide powder was less than 20nm. The synthesized composite powders were also subjected to a hydrogen heat treatment to fully carburize WC1−x , W2C, and W phases to the WC phase as well as to remove excess carbon in the product. Finally nanosized WC–Co composite powder of particle size less than 100nm was obtained. [Copyright &y& Elsevier]