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A purely ab initio spectroscopic quality quartic force field for acetylene.

Authors :
Martin, Jan M.L.
Lee, Timothy J.
Source :
Journal of Chemical Physics. 1/8/1998, Vol. 108 Issue 2, p676. 16p. 9 Charts.
Publication Year :
1998

Abstract

Assesses the spectroscopic quality of quartic force field for acetylene. Details on coupled cluster with all single and double substitutions and quasiperturbative inclusion of connected Triple excitations method; Bending modes of carbon-carbon multiple bonds; Computations on quartic force field and harmonic frequencies.

Details

Language :
English
ISSN :
00219606
Volume :
108
Issue :
2
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
4132829
Full Text :
https://doi.org/10.1063/1.475429