Combining cosmogenic nuclides and major elements from moraine soil profiles to improve weathering rate estimates

Abstract: Previous studies of chemical weathering rates for soil developed on glacial moraines generally assumed little or no physical erosion of the soil surface. In this study, we investigate the influence of physical erosion on soil profile weathering rate calculations. The calculation of chemical weathering rates is based on the assumption that soil profiles represent the integrated amount of weathering since the time of moraine deposition. The weathering rate of a surface subjected to denudation is the sum of the weathering loss from the existing soil profile added to the weathering loss in the material removed by denudation, divided by the deposition age. In this study, the amount of weathered material removed since moraine deposition is calculated using the denudation rate estimated from cosmogenic nuclide data and the deposition age of the moraine. Weathering rates accounting for denudation since moraine deposition are compared to weathering rates based on the assumption of no physical erosion and on the assumption of steady-state denudation for the Type Pinedale moraine (∼21 ka) and the Bull Lake-age moraine (∼140 ka) in the Fremont Lake Area (Wind River Mountains, Wyoming, USA). The total weathering rates accounting for denudation are 8.15±1.05 g(oxide) m− 2 y− 1 for the Type Pinedale moraine and 4.78±0.89 g(oxide) m− 2 y− 1 for the Bull Lake-age moraine, which are ∼2 to 4 times higher, respectively, than weathering rates based on the assumption of no physical erosion. The weathering rates based on denudation since moraine deposition are comparable or smaller than weathering rates assuming steady-state denudation. We find the assumption of steady-state denudation is not valid in depositional landscapes with young deposition ages or slow denudation rates. The decrease in weathering rates over time between the Type Pinedale and Bull Lake-age soils that is observed in the case of no physical erosion is decreased when the influence of denudation on the total weathering rates is taken into account. Fresh unweathered material with high reactive mineral surface area is continuously provided to the surface layer by denudation diminishing the effect of decreasing weathering rate over time. [Copyright &y& Elsevier]