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Effect of substituents on electronic properties, thin film structure and device performance of dithienothiophene–phenylene cooligomers
- Source :
-
Thin Solid Films . Mar2009, Vol. 517 Issue 9, p2968-2973. 6p. - Publication Year :
- 2009
-
Abstract
- Abstract: Dithienothiophene-phenylene cooligomers with n-hexyloxy or n-dodecyloxy substituents have been synthesized and compared to the previously reported unsubstituted parent compound. The effect of substituents on the thermal, electronic, optical, thin film structure and field-effect transistor (OFET) properties was investigated. Structural phase transitions from highly-ordered nanocrystalline to liquid crystalline were observed at 241 and 213 °C for n-hexyloxy- and n-dodecyloxy-substituted compounds respectively, different from the parent compound. For the alkoxy-substituted compounds, the absorption spectra in thin film blue shift 50 nm, while the fluorescence spectra in thin film red shift 88–100 nm compared to those in solution. The OFET devices based on the alkoxy-substituted compounds exhibit mobilities as high as ca 0.02 cm2V−1s−1 and their performance is sensitive to the alkoxy substituents and substrate temperatures. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00406090
- Volume :
- 517
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Thin Solid Films
- Publication Type :
- Academic Journal
- Accession number :
- 36563879
- Full Text :
- https://doi.org/10.1016/j.tsf.2008.11.102