Diameter-selective separation of double-walled carbon nanotubes.

Here, we report a simple and effective way of separating double-walled carbon nanotubes as a function of their diameter using individually dispersed nanotube solutions with the aid of long and random single-stranded DNA. The subtle pH change in nanotube solutions gives rise to the preferential coagulation of large-diameter tubes and allows the easy preparation of small-diameter tubes. The stronger van der Waals forces between large-diameter tubes, combined with the decreased solubility of DNA in water at low pH, lead to the preferential agglomeration of large-diameter tubes. [ABSTRACT FROM AUTHOR]