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Ratiometric multimodal chemosensors based on cubic silsesquioxanes for monitoring solvent polarity

Authors :
Tanaka, Kazuo
Inafuku, Kenichi
Chujo, Yoshiki
Source :
Bioorganic & Medicinal Chemistry. Dec2008, Vol. 16 Issue 23, p10029-10033. 5p.
Publication Year :
2008

Abstract

Abstract: We report the multi-functionalized cubic silsesquioxane (POSS) as the ratiometric multimodal chemosensors for monitoring solvent polarity with fluorescence and 19F NMR. The alteration of the dispersion state of the modified POSS by changing solvent polarity can be reflected into the orthogonal signal responses for the fluorescence and 19F NMR. In addition, the ratiometric dual monitoring for the enzymatic reaction was performed using the POSS-based chemosensor. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
09680896
Volume :
16
Issue :
23
Database :
Academic Search Index
Journal :
Bioorganic & Medicinal Chemistry
Publication Type :
Academic Journal
Accession number :
35326517
Full Text :
https://doi.org/10.1016/j.bmc.2008.10.016