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Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands.
- Source :
-
Journal of Coordination Chemistry . Nov2008, Vol. 61 Issue 22, p3525-3533. 9p. 1 Diagram, 7 Charts, 3 Graphs. - Publication Year :
- 2008
-
Abstract
- A series of planar Ni(II) dithiolenes derived from maleonitriledithiole (mnt), benzene-1,2-dithiole (bdt) and 1-toluene-3,4-dithiole (tdt) with bidentate N,N-ligands (bpy = 2,2'-bipyridine; phen = 1,10-phenanthroline, nphen = 5-nitro-1,10-phenanthroline) of the [Ni(N,N)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(phen)(bdt)] confirmed a planar geometry of NiN2S2. Possible practical applications such as use for vulcanization catalytic agents and for their anticholinesterase activity were evaluated. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 61
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 34870987
- Full Text :
- https://doi.org/10.1080/00958970802105326