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Photolytic aziridination by thianthrene sulfilimine derivatives.
- Source :
-
Journal of Sulfur Chemistry . Oct2008, Vol. 29 Issue 5, p459-465. 7p. 3 Charts. - Publication Year :
- 2008
-
Abstract
- Photolyses of thianthrene sulfilimine derivatives in the presence of several olefins were studied and found to afford the corresponding aziridines in good yields, particularly, in case of 2,8-dibromo-[5-(N-tosyl)imino]thianthrene. This reaction was considered to proceed via generation of nitrene by photolytic S-N bond cleavage of thianthrene sulfilimines. Further, photo-aziridination of olefins by thianthrene sulfilimine derivatives was intensively studied to make clear the ability as nitrene precursors. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SULFILIMINES
*IMINES
*ORGANOSULFUR compounds
*AZIRIDINES
*HETEROCYCLIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 17415993
- Volume :
- 29
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Journal of Sulfur Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 34773661
- Full Text :
- https://doi.org/10.1080/17415990802183868