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Malonaldehyde Synthesis.

Authors :
Trivella, Aurélien
Coussan, Stéphane
Chiavassa, Thierry
Source :
Synthetic Communications. 2008, Vol. 38 Issue 19, p3285-3290. 6p. 3 Diagrams, 2 Graphs.
Publication Year :
2008

Abstract

Pure malonaldehyde is obtained by organic synthesis. In the first step, malonaldehyde sodium salt is obtained by 1,1,3,3-tetramethoxypropane acidic hydrolysis and purified by recrystallization in methanol/ether. In the second step, malonaldehyde is synthesized by reaction between malonaldehyde sodium salt and gaseous hydrochloric acid dissolved in ether at - 40 °C. Finally, malonaldehyde is purified by pumping at temperatures less than 0 °C and extracted by sublimation. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00397911
Volume :
38
Issue :
19
Database :
Academic Search Index
Journal :
Synthetic Communications
Publication Type :
Academic Journal
Accession number :
34280742
Full Text :
https://doi.org/10.1080/00397910802122433