1,4-Cyclohexadiene with Pd/C as a rapid, safe transfer hydrogenation system with microwave heating

Authors :: Quinn, John F.
Razzano, Dana A.
Golden, Kathryn C.
Gregg, Brian T.
Source :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Oct2008, Vol. 49 Issue 42, p6137-6140. 4p.
Publication Year :: 2008
Abstract: Abstract: A method for the rapid, safe hydrogenation of alkenes and deprotection of benzyl ethers and carboxybenzyl amides is described using catalytic transfer hydrogenation under microwave heating conditions. Commonly available Pd/C catalyst is extremely effective with 1,4-cyclohexadiene as the hydrogen transfer source. In general, the reactions are complete within five minutes at 100°C. [Copyright &y& Elsevier]

Subjects :: *PALLADIUM catalysts
*QUINONE
*MICROWAVE heating
*HYDROGENATION
*ALKENES
*ETHERS
*AMIDES

Language :: English
ISSN :: 00404039
Volume :: 49
Issue :: 42
Database :: Academic Search Index
Journal :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :: Academic Journal
Accession number :: 34200076
Full Text :: https://doi.org/10.1016/j.tetlet.2008.08.023

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