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Surprisingly Long-Lived Ascorbyl Radicals in Acetonitrile: Concerted Proton—Electron Transfer Reactions and Thermochemistry.
- Source :
-
Journal of the American Chemical Society . 6/18/2008, Vol. 130 Issue 24, p7546-7547. 2p. 2 Diagrams. - Publication Year :
- 2008
-
Abstract
- The article describes a number of concerted proton-electron transfer (CPET) reactions of ascorbates in MeCN, which reveal an unusual solvent dependence of the O-H bond dissociation free energy. It concludes that ascorbyl radical is readily generated from the corresponding ascorbate by phenoxyl and nitroxyl radicals.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 130
- Issue :
- 24
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 34106836
- Full Text :
- https://doi.org/10.1021/ja802055t