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Total Synthesis of Crisamicin A.
- Source :
-
Organic Letters . May2008, Vol. 10 Issue 14, p3017-3020. 4p. - Publication Year :
- 2008
-
Abstract
- Stereoselective total synthesis of natural product crisamicin A ( 1) was accomplished for the first time via the Pd/TMTU-catalyzed alkoxycarbonylative annulation to generate a unique cis-pyran-fused lactone, an intermolecular Diels−Alder reaction to construct the pyranonaphthoquinone unit, and a novel Pd−thiourea pincer complex-catalyzed homocoupling of functionalized naphthoquinones. [ABSTRACT FROM AUTHOR]
- Subjects :
- *HETEROCYCLIC compounds
*ORGANOSULFUR compounds
*DOXEPIN
*LISURIDE
Subjects
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 10
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 33200792
- Full Text :
- https://doi.org/10.1021/ol800977n