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Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes.
- Source :
-
Pure & Applied Chemistry . May2008, Vol. 80 Issue 5, p1079-1087. 9p. - Publication Year :
- 2008
-
Abstract
- Paper based on a presentation at the 14th International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-14), 2-6 August 2007, Nara, Japan. Other presentations are published in this issue, pp. 807-1194A new protocol for CO gas-free carbonylation, in which aldehydes are used as a substitute for CO, is described. The protocol consists of two Rh-mediated processes; the Rh-mediated decarbonylation of aldehydes, which leads to the formation of Rh carbonyl, and subsequent Rh-catalyzed carbonylative cyclization utilizing the in situ formed Rh carbonyl species. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CONFERENCES & conventions
*ORGANIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 00334545
- Volume :
- 80
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Pure & Applied Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 33004284
- Full Text :
- https://doi.org/10.1351/pac200880051079