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A series of stable salts of the oxidized donors TTF, o-Me2TTF, TMTTF, and TTF(SCH2CH2CN)4
- Source :
-
Synthetic Metals . Jul2008, Vol. 158 Issue 11, p447-452. 6p. - Publication Year :
- 2008
-
Abstract
- Abstract: Reactions of the organic donors tetrathiafulvalene (TTF), o-dimethyltetrathiafulvalene (o-Me2TTF), tetramethyltetrathiafulvalene (TMTTF), and tetrathiafulvalene tetrathiolate [TTF(SCH2CH2CN)4] with oxidizing agents of suitable potential resulted in the formation of stable salts in which the donors are present in their monocationic radical forms. The salts presented herein represent a series of reagents containing oxidized chalcofulvalene donors that can be used as starting materials for metathesis reactions with other cations. All of the salts were characterized by X-ray crystallography and UV–vis–NIR spectroscopy. [Copyright &y& Elsevier]
- Subjects :
- *CRYSTALLOGRAPHY
*MINERALOGY
*SPECTRUM analysis
*OXIDIZING agents
Subjects
Details
- Language :
- English
- ISSN :
- 03796779
- Volume :
- 158
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Synthetic Metals
- Publication Type :
- Academic Journal
- Accession number :
- 32843584
- Full Text :
- https://doi.org/10.1016/j.synthmet.2008.03.008