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Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex.
- Source :
-
Organometallics . Mar2008, Vol. 27 Issue 8, p1667-1670. 4p. - Publication Year :
- 2008
-
Abstract
- Pd(OAc) 2-mediated dehydrogenation of an alkyl group to a double bond or a η 3-allylic complex via sp 3C−H bond activation and allylic oxidation is reported. A novel redox is proposed for this double oxidation under oxidant-free conditions. A catalytic protocol using benzoquinone as the stoichiometric oxidant has also been developed for the dehydrogenation of cyclopentylcarboxamides. [ABSTRACT FROM AUTHOR]
- Subjects :
- *OXIDATION
*DEHYDROGENATION
*ALKYLATING agents
*PROPENE
Subjects
Details
- Language :
- English
- ISSN :
- 02767333
- Volume :
- 27
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Organometallics
- Publication Type :
- Academic Journal
- Accession number :
- 32793918
- Full Text :
- https://doi.org/10.1021/om8000444