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The Analysis of Synergistic Effects of Zeolites applied in Intumescent Halogen-free Flame-retardant ABS Composites.
- Source :
-
Polymer-Plastics Technology & Engineering . Jun2008, Vol. 47 Issue 6, p613-618. 6p. 2 Diagrams, 2 Charts, 2 Graphs. - Publication Year :
- 2008
-
Abstract
- Ammonium polyphosphate (APP) and pentaerythritol (PER) were selected to form intumescent flame-retardant (IFR) and halogen-free flame-retardant ABS/IFR/zeolite composites were prepared by melt blending. The influences of zeolite 4A, 13X on thermal behavior of mass loss, flame-retardant performance, microstructure, mechanical properties, and processability of composites were investigated. The results showed that zeolite 4A with a lower Si/Al ratio, stronger surface polarity, and lower loading not only had a better synergistic effect with IFR, which promoted the catalytic esterification of IFR, stabilized the charred residue, and made ABS/IFR composites possess higher flame-retardant performance, but also was beneficial to improving the mechanical properties and processability of composites. When the content of zeolite 4A was 1 wt%, ABS/IFR composites had better comprehensive properties. Its limiting oxygen index (LOI) value, impact strength, tensile strength, flexural strength, modulus, and melt index were 32.6%, 3.4 KJ/m2, 39 MPa, 38.7 MPa, 1337 MPa, and 24.5 g/10 min, respectively. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03602559
- Volume :
- 47
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Polymer-Plastics Technology & Engineering
- Publication Type :
- Academic Journal
- Accession number :
- 32746615
- Full Text :
- https://doi.org/10.1080/03602550802059733