Synthesis of the seed germination stimulant 3-methyl-2H-furo[2,3-c]pyran-2-ones utilizing direct and regioselective Ti-crossed aldol addition

Authors :: Nagase, Ryohei
Katayama, Mayumi
Mura, Hiroaki
Matsuo, Noritada
Tanabe, Yoo
Source :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Jul2008, Vol. 49 Issue 29/30, p4509-4512. 4p.
Publication Year :: 2008
Abstract: Abstract: 3-Methyl-2H-furo[2,3-c]pyran-2-ones 1 and 2, a unique and remarkable seed germination stimulant, and its analogue were synthesized using direct and regioselective Ti-crossed aldol addition between dihydro-2H-pyran-3(4H)-ones and methyl pyruvate as the key step, followed by furanone formation. [Copyright &y& Elsevier]

Language :: English
ISSN :: 00404039
Volume :: 49
Issue :: 29/30
Database :: Academic Search Index
Journal :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :: Academic Journal
Accession number :: 32639244
Full Text :: https://doi.org/10.1016/j.tetlet.2008.05.052

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