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Rare-Earth Metal Alkyl and Hydride Complexes Stabilized by a Cyclen-Derived [NNNN] Macrocyclic Ancillary Ligand.

Authors :
Ohashi, Masato
Konkol, Marcin
Del Rosal, Iker
Poteau, Romuald
Maron, Laurent
Okuda, Jun
Source :
Journal of the American Chemical Society. 6/4/2008, Vol. 130 Issue 22, p6920-6921. 2p. 3 Diagrams.
Publication Year :
2008

Abstract

The article discusses the result of a study concerning rare earth metal alkyl and hydride complexes stabilized by a cyclen-driven macrocyclic ancillary ligand. Me3TACD ligand was introduced as a monoanionic ancillary environment for the stabilization of rare earth metal alkyl and hydride with properties distinct from other monoanionic ligands.

Details

Language :
English
ISSN :
00027863
Volume :
130
Issue :
22
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
32553650
Full Text :
https://doi.org/10.1021/ja801771u