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Solvothermal Synthesis and Characterization, of Two High-Nuclearity Mixed-Valent Manganese Phosphonate Clusters.
- Source :
-
Inorganic Chemistry . 5/5/2008, Vol. 47 Issue 9, p3489-3491. 3p. 8 Diagrams, 1 Graph. - Publication Year :
- 2008
-
Abstract
- Two novel mixed-valent manganese (MnII/MnIII) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn19 cluster with a cylindrical core structure. Compound 2 possess a Mn16 core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 47
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 32181351
- Full Text :
- https://doi.org/10.1021/ic8001493