Luminescent Langmuir–Blodgett film of a new amphiphilic Eu3+ β-diketonate

Abstract: This work reports on the synthesis and characterization of the ligand 3-hexadecylpentane-2,4-dione (Hhdacac) and its Eu3+ complexes Eu(hdacac)6·2H2O, Eu(hdacac)6·phen and Eu(hdacac)6·tta, where phen and tta denote 1,10-phenanthroline and thenoyltrifluoroacetone, respectively. These new compounds present long carbon chains and their expected miscibility into non-polar ambients is confirmed by the emission spectra of Eu(hdacac)6·tta in hexane. Moreover, the amphiphilic properties of Eu(hdacac)6 complexes allow the obtainment of thin luminescent films by the Langmuir–Blodgett technique. In both cases (solids and films), the typical antenna effect of β-diketonates is observed. The alluring characteristics of these compounds raise great interest in many fields of Materials Science, like photo- and electro-luminescent materials (mainly thin “organic” films), metal catalysts or probes in non-polar solutions, and Langmuir–Blodgett films of several compositions. For the characterization of these products, nuclear magnetic resonance spectroscopy (1H NMR), thermogravimetric analysis, elementary analyses (C, H), scanning electron microscopy (energy dispersive X-ray spectroscopy), absorption (UV–vis/FT–IR) and photoluminescence spectroscopies were used. [Copyright &y& Elsevier]