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Stereocontrol by a Pair of Epimeric Sugar-Derived Ligands of the Coordination Sphere of Copper(Il) Complexes.
- Source :
-
Inorganic Chemistry . 4/7/2008, Vol. 47 Issue 7, p2243-2245. 3p. 2 Diagrams, 1 Chart, 2 Graphs. - Publication Year :
- 2008
-
Abstract
- A pair of novel C3-epimeric sugar-derived ligands (glycoligands) with a neutral N40 donor set was synthesized. Copper(ll) complexes of both ligands were obtained and characterized by X-ray crystallography. Cyclic voltammetry, electron paramagnetic resonance, and UV-vis spectroscopies showed similar electronic properties. Mirror-image CD spectra were obtained for the Cu" d-d band, indicating an enantiomeric character of the coordination sphere, which has been rationalized structurally. This example shows the possible predetermination of stereochemistry for complexes by ligands based on a glycoscaffold. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 47
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 31989775
- Full Text :
- https://doi.org/10.1021/ic702209g