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7-Chloro-3-ethyl-9,9-dimethyl-2-tosyl-2,3,3a,4,9,9a-hexahydro-1H-pyrrolo[3,4-b]quinoline.

Authors :
Sudha, D.
Chinnakali, K.
Jayagobi, M.
Raghunathan, R.
Hoong-Kun Fun
Source :
Acta Crystallographica: Section E. Dec2007, Vol. 63 Issue 12, po4912-sup15. 18p. 7 Diagrams, 5 Charts.
Publication Year :
2007

Abstract

The asymmetric unit of the title compound, C22H27ClN2O2S, consists of two independent molecules, A and B, with similar conformations. In both molecules, the pyrrolidine rings adopt twist conformations and the tetrahydropyridine rings have half-chair conformations; these rings are trans-fused. In molecule A, the tosyl group is attached equatorially to the pyrrolidine ring, whereas in molecule B it is in a biaxial position. In both molecules, the sulfonyl groups have distorted tetrahedral geometries. Molecules A and B are linked into a two-dimensional network parallel to the ab plane by N—H⋯O and C—H⋯O hydrogen bonds, and C—H⋯π interactions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
12
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
31911484
Full Text :
https://doi.org/10.1107/S1600536807061351