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7-Chloro-3-ethyl-9,9-dimethyl-2-tosyl-2,3,3a,4,9,9a-hexahydro-1H-pyrrolo[3,4-b]quinoline.
- Source :
-
Acta Crystallographica: Section E . Dec2007, Vol. 63 Issue 12, po4912-sup15. 18p. 7 Diagrams, 5 Charts. - Publication Year :
- 2007
-
Abstract
- The asymmetric unit of the title compound, C22H27ClN2O2S, consists of two independent molecules, A and B, with similar conformations. In both molecules, the pyrrolidine rings adopt twist conformations and the tetrahydropyridine rings have half-chair conformations; these rings are trans-fused. In molecule A, the tosyl group is attached equatorially to the pyrrolidine ring, whereas in molecule B it is in a biaxial position. In both molecules, the sulfonyl groups have distorted tetrahedral geometries. Molecules A and B are linked into a two-dimensional network parallel to the ab plane by N—H⋯O and C—H⋯O hydrogen bonds, and C—H⋯π interactions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *MOLECULES
*PYRROLIDINE
*GEOMETRY
*HYDROGEN bonding
*SULFONYL chlorides
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 63
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 31911484
- Full Text :
- https://doi.org/10.1107/S1600536807061351