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Hydrogen-bonding patterns in the cocrystal 2-amino-4,6-dimethylpyrimidine--terephthalic acid (2/1).

Authors :
Devi, Periasamy
Muthiah, Packianathan Thomas
Source :
Acta Crystallographica: Section E. Dec2007, Vol. 63 Issue 12, po4822-sup9. 12p. 7 Diagrams, 5 Charts.
Publication Year :
2007

Abstract

In the crystal structure of the title compound, 2C6H9N3 C8H6O4, terephthalic acid has a crystallographic inversion centre and the dimethylpyrimidine molecule shows approximate non-crystallographic mirror and twofold rotation symmetry. The inversion-related pyrimidine molecules form a base pair [R2 2(8) ring motif] via a pair of NH⋯N hydrogen bonds. The carboxyl groups of terephthalic acid link the base pairs via OH⋯N and NH⋯O hydrogen bonds [R2 2(8) motif] to generate a supramolecular ribbon. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
12
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
31911442
Full Text :
https://doi.org/10.1107/S1600536807059703