Back to Search
Start Over
General Preparation and Controlled Cyclization of Acyclic Terpenoids.
- Source :
-
Journal of Organic Chemistry . 3/7/2008, Vol. 73 Issue 5, p1991-1994. 4p. 1 Chart. - Publication Year :
- 2008
-
Abstract
- A general preparation method of the all-(E)-polyprenols 12 has been developed from readily available geranyl sulfone by the chain-extension process utilizing the C5 unit 5 and the chain-termination process utilizing the C5 unit 10 together with the chemoselective reductive desulfonylation. The polyprenols 12 were converted to compounds 3 containing two consecutive prenyl sulfone moieties at the tail end, which underwent the controlled electrophilic cyclization only at the carbon-carbon double bonds that were remote from the flat and rigid benzenesulfonyl groups. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 73
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 31220165
- Full Text :
- https://doi.org/10.1021/jo702303a