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Unravelling the Complexities of Polyoxometalates in Solution Using Mass Spectrometry: Protonation versus Heteroatom Inclusion.

Authors :
De-Liang Long
Streb, Carsten
Yu-Fei Song
Mitchell, Scott
Cronin, Leroy
Source :
Journal of the American Chemical Society. 2/13/2008, Vol. 130 Issue 6, p1830-1832. 3p. 5 Graphs.
Publication Year :
2008

Abstract

The article presents a study on the use of mass spectrometry in the study of polyoxometalates solutions. It mentions that the determination of the structures of polyoxometalate clusters has remained a problem due to the complexities of protonation states. The study uses mass spectrometry to determine the degree of protonation and number of heteroanions in polyoxometalates solutions. An overview of the study is provided.

Details

Language :
English
ISSN :
00027863
Volume :
130
Issue :
6
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
29986196
Full Text :
https://doi.org/10.1021/ja075940z