Back to Search
Start Over
Theoretical study of the aggregation of d10–s2 Au(I)–Tl(I) complexes in extended unsupported chains
- Source :
-
Journal of Molecular Structure: THEOCHEM . Feb2008, Vol. 851 Issue 1-3, p121-126. 6p. - Publication Year :
- 2008
-
Abstract
- Abstract: Model compounds are used to study the metallophilic attraction between gold and thallium atoms. Ab initio calculations on dimers and tetramers in different distributions of the minimal units are analyzed. An attraction is found for all models and there is a reasonable agreement between the experimental and theoretical geometries at the HF and MP2 levels. [Copyright &y& Elsevier]
- Subjects :
- *GOLD
*THALLIUM
*DIMERS
*TETRAMERS (Oligomers)
Subjects
Details
- Language :
- English
- ISSN :
- 01661280
- Volume :
- 851
- Issue :
- 1-3
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Structure: THEOCHEM
- Publication Type :
- Academic Journal
- Accession number :
- 29375685
- Full Text :
- https://doi.org/10.1016/j.theochem.2007.11.004