CO2 activation of ordered porous carbon CMK-1 for hydrogen storage

Abstract: Porous carbons with large surface areas and pore volumes, as well as relatively uniform micropore texture were prepared by CO2 activation of ordered porous carbon CMK-1 for hydrogen storage. Both activation temperature and time were studied. The structure and texture changes in the carbons were investigated by using XRD and nitrogen sorption. Under the optimum condition that treating with CO2 at 950°C for 6h, a high H2 uptake of 2.19wt% was obtained at 77K and 1bar. The capacity is almost twice that of CMK-1 and higher than that of the reported porous carbons synthesized by silica templates. The pores smaller than 1nm were confirmed to be the most efficient for hydrogen sorption. Besides, high efficiency of surface areas and micropores were got for the H2 uptake at 77K and 1bar. [Copyright &y& Elsevier]