On the origin of ferromagnetism in oximato-based [Mn3O]7+ triangles.

Authors :: Joan Cano
Thomas Cauchy
Eliseo Ruiz
Constantinos J. Milios
Constantinos C. Stoumpos
Theocharis C. Stamatatos
Spyros P. Perlepes
George Christou
Euan K. Brechin
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. Dec2007, Vol. 2008 Issue 2, p234-240. 7p.
Publication Year :: 2007
Abstract: DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the ‘non-planarity’ of the bridging oxime ligands and the non-parallel alignment of the Jahn–Teller axes. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 2008
Issue :: 2
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 28166150

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