Effect of calcination temperature on CrO x –Y2O3 catalysts for fluorination of 2-chloro-1,1,1-trifluoroethane to 1,1,1,2-tetrafluoroethane

Abstract: A series of CrO x –Y2O3 catalysts were prepared by a deposition–precipitation method and tested for the fluorination of 2-chloro-1,1,1-trifluoroethane (CF3CH2Cl) to synthesize 1,1,1,2-tetrafluoroethane (CF3CH2F). The highest activity was obtained on a pre-fluorinated catalyst calcined at 400 °C, with 19% of CF3CH2Cl conversion at 320 °C. The effect of the calcination temperature on the CrO x species was investigated. X-ray diffraction and Raman results indicated that the CrO x species (Cr(VI)) were well dispersed on the catalyst surface when the catalyst was calcined at 400 °C. With increasing calcination temperature, most of the CrO x species changed from high oxidation state Cr(VI) to low oxidation state Cr(V) or Cr(III) species, which resulted in difficulty in pre-fluorination of the catalyst. It was also found that the CrF x , CrO x F y or Cr(OH) x F y phases originated from high oxidation state Cr(VI) species were the active sites for the fluorination reaction. [Copyright &y& Elsevier]