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4- tert-Butyl-2-{[( E)-2,6-diisopropylphenylimino]methyl}-6-(1-phenylethyl)phenol.
- Source :
-
Acta Crystallographica: Section E . Nov2007, Vol. 63 Issue 11, po4400-o4400. 1p. 2 Diagrams, 1 Chart. - Publication Year :
- 2007
-
Abstract
- The title compound, C31H39NO, was prepared by the condensation of 5- tert-butyl-2-hydroxy-3-(1-phenylethyl)benzaldehyde with 2,6-diisopropylphenylamine in refluxing ethanol. The phenol ring and the phenylimino ring are approximately perpendicular, forming a dihedral angle of 81.5 (3)°. The phenyl ring makes a dihedral angle of 75.2 (2)° with the phenol ring and also makes a dihedral angle of 62.9 (3)° with the phenylimino ring. The molecular structure is stabilized by an intramolecular O—H...N hydrogen bond linking the phenol OH group and the phenylimino N atom. One of the isopropyl groups is disordered over two positions; the site occupancies are 0.55 and 0.45. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 63
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 27533434
- Full Text :
- https://doi.org/10.1107/S1600536807051306