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Linear oxalato- and 4,4'-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis.
- Source :
-
Journal of Coordination Chemistry . 12/1/2007, Vol. 60 Issue 23, p2527-2532. 6p. 2 Diagrams, 2 Charts. - Publication Year :
- 2007
-
Abstract
- The reaction of 1,3-bis(pyridyl-4-ylthio)propan-2-one with Cu(ClO4)2 · 6H2O gave a new complex {[Cu2(4PDS)2(ox)(H2O)4](ClO4)2}n (4PDS = 4,4'-dipyridyldisulfide, ox = oxalate), with 4PDS and ox being created by the Cu(II)-assisted oxidation of 1,3-bis(pyridyl-4-ylthio)propan-2-one. The complex determined by X-ray crystallography is a 1D polymer, in which metallacycles formed by two 4PDS and two Cu(II) ions are further bridged through ox anions. It crystallizes in the orthorhombic system, space group Fddd, with lattice parameters a = 15.106(2), b = 23.667(4), c = 27.637(3) Å and Z = 8. [ABSTRACT FROM AUTHOR]
- Subjects :
- *COPPER compounds
*POLYMERS
*X-ray crystallography
*ANIONS
*OXIDATION
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 60
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 27216945
- Full Text :
- https://doi.org/10.1080/00958970701278240